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초록
BiCl3/Ga was found to be a mild, efficient, and chemoselective system for the debromination of a series of functionally and structurally various vic-dibromides. A broad range of functional groups (ester, carboxy, aldehyde, methoxy, chloro, and ketone) was tolerated under the reaction conditions and only trans olefins were obtained in good yields.
키워드
Alkene; bismuth; debromination; gallium; DEOXYGENATION; MILD; SULFOXIDES
- 제목
- FACILE AND EFFICIENT METHOD FOR THE DEBROMINATION OF vic-DIBROMIDES TO ALKENES WITH BiCl3/Ga SYSTEM
- 저자
- Yoo, Byung Woo; Kim, Seo Hee; Park, Young Kwang
- 발행일
- 2012
- 유형
- Article
- 권
- 42
- 호
- 11
- 페이지
- 1632 ~ 1636