Morphology controlled nanocrystalline CsPbBr3 thin-film for metal halide perovskite light emitting diodes

  • Kim, B.W.
  • Heo, J.H.
  • Park, J.K.
  • Lee, D.S.
  • Park, H.
  • ... Im, S.H.
  • 외 2명
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초록

Morphology and crystal grain size of inorganic CsPbBr3 metal halide perovskite (MHP) films are controllable through a diffusion-controlled anti-solvent dripping crystallization method using an anti-solvent mixture of toluene (Tol):isopropanol (IPA). The 8:2 (v:v) Tol:IPA anti-solvent enables the production of a pinhole-free CsPbBr3 MHP film with the smallest crystal grain size and the brightest photoluminescence (PL). Accordingly, the 8:2 CsPbBr3 MHP film reveals a very uniform and strong PL mapping image. As a result, the 8:2 CsPbBr3 MHP light emitting diode (LED) exhibits ∼12.8, ∼7.4, and ∼7.9 fold enhanced maximum electroluminescence (ELmax), current efficiency (CEmax), and external quantum efficiency (EQEmax) compared to the 10:0 pristine device. The optimized 8:2 MHP LED shows an ELmax of 22,298 cd/m2, CEmax of 36.65 cd/A and EQEmax of 9.64%, respectively. In addition, the 8:2 CsPbBr3 MHP LED with controlled morphology and grain size has better operating stability than the pristine device. © 2021 The Korean Society of Industrial and Engineering Chemistry

키워드

Anti-solvent drippingCrystallizationDiffusionInorganic metal halide perovskiteLight emitting diodeQUANTUM DOTSBRIGHTLUMINESCENCEPERFORMANCE
제목
Morphology controlled nanocrystalline CsPbBr3 thin-film for metal halide perovskite light emitting diodes
저자
Kim, B.W.Heo, J.H.Park, J.K.Lee, D.S.Park, H.Kim, S.Y.Kim, J.H.Im, S.H.
DOI
10.1016/j.jiec.2021.02.028
발행일
2021-05-25
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
97
페이지
417 ~ 425