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Cyanide-Bridged (WMnIII)-Mn-v Single-Chain Magnet with Isolated Mn-III Moieties Exhibiting Two Types of Relaxation Dynamics
- Yoon, Jung Hee;
- Lee, Jin Wuk;
- Ryu, Dae Won;
- Choi, Sang Yup;
- Yoon, Sung Won;
- ... Hong, Chang Seop;
- 외 3명
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A 5d-3d bimetallic compound was prepared by self-assembling [W(CN)(8)](3-) and the Mn-III Schiff bases. This neutral complex consists of cyanide-linked anionic chains and isolated Mn-III Schiff base cations. We demonstrate that two types of relaxation processes are involved in the system; the low-T dynamics may come from magnetic domain dynamics and the high-T relaxation stems from the anionic chain, revealing single-chain magnet character.
키워드
MOLECULE-MAGNET; EXCHANGE; MO; BEHAVIOR; FE
- 제목
- Cyanide-Bridged (WMnIII)-Mn-v Single-Chain Magnet with Isolated Mn-III Moieties Exhibiting Two Types of Relaxation Dynamics
- 저자
- Yoon, Jung Hee; Lee, Jin Wuk; Ryu, Dae Won; Choi, Sang Yup; Yoon, Sung Won; Suh, Byoung Jin; Koh, Eui Kwan; Kim, Hyoung Chan; Hong, Chang Seop
- 발행일
- 2011-11-21
- 유형
- Article
- 권
- 50
- 호
- 22
- 페이지
- 11306 ~ 11308