Novel Optical/Electrochemical Selective 1,2,3-Triazole Ring-Appended Chemosensor for the Al3+ Ion

  • Kim, Sang Hoon
  • Choi, Hong Seok
  • Kim, Joohoon
  • Lee, Suk Joong
  • Quang, Duong Tuan
  • ... Kim, Jong Seung
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초록

A chemosensor (1) bearing a 1,2,3-triazole ring spacer was synthesized for the selective detection of Al3+ with respect to dual optical and electrochemical changing events. The addition of Al+ ions to 1 induced a significant change in fluorescence intensity, attributable to ICT and CHEF effects from the 1,2,3-triazole ring. The electrochemical behavior of 1 in the presence of the Al3+ ion was significantly altered compared with those of the other metal cations tested.

키워드

FLUORESCENCE DETECTIONBINDING-SITESLARIAT ETHERSANTHRAQUINONEALUMINUMSENSORELECTROCHEMISTRYDERIVATIVESSPIROPYRANBEHAVIOR
제목
Novel Optical/Electrochemical Selective 1,2,3-Triazole Ring-Appended Chemosensor for the Al3+ Ion
저자
Kim, Sang HoonChoi, Hong SeokKim, JoohoonLee, Suk JoongQuang, Duong TuanKim, Jong Seung
DOI
10.1021/ol902743s
발행일
2010-02-05
유형
Article
저널명
Organic Letters
12
3
페이지
560 ~ 563