Octacyanometalate-Based Ferrimagnetic (MMnIII)-Mn-V (M = Mo, W) Bimetallic Chain Racemates with Slow Magnetic Relaxations

  • Yoo, Houng Sik; 
  • Ko, Hyun Hee; 
  • Ryu, Dae Won; 
  • Lee, Jin Wuk; 
  • Yoon, Jung Hee; 
  • ... Hong, Chang Seop; 
  • 외 3명
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초록

Cyanide-bridged M-V-Mn-III (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Wit Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.

키워드

SINGLE-MOLECULE MAGNET; CRYSTAL-STRUCTURES; FERROMAGNETIC INTERACTIONS; COMPLEXES; CLUSTER; DESIGN; CUBE
제목
Octacyanometalate-Based Ferrimagnetic (MMnIII)-Mn-V (M = Mo, W) Bimetallic Chain Racemates with Slow Magnetic Relaxations
저자
Yoo, Houng Sik; Ko, Hyun Hee; Ryu, Dae Won; Lee, Jin Wuk; Yoon, Jung Hee; Lee, Woo Ram; Kim, Hyoung Chan; Koh, Eui Kwan; Hong, Chang Seop
DOI
10.1021/ic900879d
발행일
2009-07-06
유형
Article
저널명
Inorganic Chemistry
권
48
호
13
페이지
5617 ~ 5619