Cellulosic Carbon Fibers with Branching Carbon Nanotubes for Enhanced Electrochemical Activities for Bioprocessing Applications

Citations

WEB OF SCIENCE

8
Citations

SCOPUS

11

초록

Renewable biobased carbon fibers are promising materials for large-scale electrochemical applications including chemical processing, energy storage, and biofuel cells. Their performance is, however, often limited by low activity. Herein we report that branching carbon nanotubes can enhance the activity of carbonized cellulosic fibers, such that the oxidation potential of NAD(H) was reduced to 0.55 V from 0.9 V when applied for bioprocessing. Coordinating with enzyme catalysts, such hierarchical carbon materials effectively facilitated the biotransformation of glycerol, with the total turnover number, of NAD(H) over 3500 within 5 h of reaction.

키워드

carbon nanotubes; cofactor regeneration; dihydroxyacetone; glycerol biotransformation; porous carbon electrode; cellulosic fibers; MICROELECTRODES
제목
Cellulosic Carbon Fibers with Branching Carbon Nanotubes for Enhanced Electrochemical Activities for Bioprocessing Applications
저자
Zhao, Xueyan; Lu, Xin; Tze, William Tai Yin; Kim, Jungbae; Wang, Ping
DOI
10.1021/am402916g
발행일
2013-09-25
유형
Article
저널명
ACS Applied Materials & Interfaces
권
5
호
18
페이지
8853 ~ 8856