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Cellulosic Carbon Fibers with Branching Carbon Nanotubes for Enhanced Electrochemical Activities for Bioprocessing Applications
- Zhao, Xueyan;
- Lu, Xin;
- Tze, William Tai Yin;
- Kim, Jungbae;
- Wang, Ping
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11초록
Renewable biobased carbon fibers are promising materials for large-scale electrochemical applications including chemical processing, energy storage, and biofuel cells. Their performance is, however, often limited by low activity. Herein we report that branching carbon nanotubes can enhance the activity of carbonized cellulosic fibers, such that the oxidation potential of NAD(H) was reduced to 0.55 V from 0.9 V when applied for bioprocessing. Coordinating with enzyme catalysts, such hierarchical carbon materials effectively facilitated the biotransformation of glycerol, with the total turnover number, of NAD(H) over 3500 within 5 h of reaction.
키워드
carbon nanotubes; cofactor regeneration; dihydroxyacetone; glycerol biotransformation; porous carbon electrode; cellulosic fibers; MICROELECTRODES
- 제목
- Cellulosic Carbon Fibers with Branching Carbon Nanotubes for Enhanced Electrochemical Activities for Bioprocessing Applications
- 저자
- Zhao, Xueyan; Lu, Xin; Tze, William Tai Yin; Kim, Jungbae; Wang, Ping
- 발행일
- 2013-09-25
- 유형
- Article
- 권
- 5
- 호
- 18
- 페이지
- 8853 ~ 8856
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 4 페이지
- ISSN
- E 1944-8252
P 1944-8244