2-Substituted Thio- and Amino-5,8-dimethoxy-1,4-naphthoquinones as a Novel Class of Acyl-CoA: Cholestrol Acyltransferase Inhibitors

  • Shen, Gui-Nan
  • Choi, Ong Ho
  • Gajulapati, Kondaji
  • Lee, Jee Hyun
  • Kim, Young Kook
  • ... Choi, Yongseok
  • 외 5명
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초록

A series of 2-alkyl or 2-arylthio-5,8-dimethoxy-1,4-naphthoquinones (2-Thio-DMNQ, 5a-s) and 2-alkylamino-5,8-dimethoxy-1,4-naphthoquinones (2-Amino-DMNQ, 6a-k) was synthesized and evaluated for their ACAT inhibitory activities. Among them, the 2-dodecylthio-DMNQ 51 and 2-isobutylamidoundodecylthio-DMNQ 5r showed the most potent ACAT inhibitory activities with IC50 value of 22.8 and 24.4 mu M, respectively. In a structure-activity relationship study, 2-thio-DMNQs with side chains of carbon number 11 similar to 15 exhibited significant ACAT inhibitory activities.

키워드

NaphthoquinonesMast cellsAcyl CoA: Cholestrol Acyl Transferase (ACAT)Structure-activity relationshipATHEROSCLEROSISMICE
제목
2-Substituted Thio- and Amino-5,8-dimethoxy-1,4-naphthoquinones as a Novel Class of Acyl-CoA: Cholestrol Acyltransferase Inhibitors
저자
Shen, Gui-NanChoi, Ong HoGajulapati, KondajiLee, Jee HyunKim, Young KookRho, Mun ChalJung, Sang-HunLee, KyeongHan, Sung SikSong, Gyu-YongChoi, Yongseok
발행일
2009-05-20
유형
Article
저널명
Bulletin of the Korean Chemical Society
30
5
페이지
1088 ~ 1092