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'Cleft-form' electrochemical anion chemosensor with amide and triazole donor groups
- Cao, Qian-Yong;
- Pradhan, Tuhin;
- Lee, Min Hee;
- Choi, Dong Hoon;
- Kim, Jong Seung
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17초록
A novel 'cleft-form' electrochemical anion receptor bearing amide and triazole donor groups, 1, has been synthesized and characterized. Among various anions, 1 shows a significant anodic shift response for H2PO4- and F-, with its multiple N-H center dot center dot center dot anion and C-H center dot center dot center dot anion interactions, which is supported by theoretical calculation and NMR titration results. (C) 2012 Elsevier Ltd. All rights reserved.
키워드
Ferrocene; 'Cleft-form' receptor; Anions sensing; MOLECULAR RECOGNITION; RECEPTOR CHEMISTRY; ARYL-TRIAZOLE; HYDROGEN-BOND; PYROPHOSPHATE; FLUORESCENT; COMPLEXES; BINDING
- 제목
- 'Cleft-form' electrochemical anion chemosensor with amide and triazole donor groups
- 저자
- Cao, Qian-Yong; Pradhan, Tuhin; Lee, Min Hee; Choi, Dong Hoon; Kim, Jong Seung
- 발행일
- 2012-09-12
- 유형
- Article
- 권
- 53
- 호
- 37
- 페이지
- 4917 ~ 4920