N-doped carbon-coated CoSe2 nanocrystals anchored on two-dimensional MXene nanosheets for efficient electrochemical sodium- and potassium-ion storage

초록

Sodium-ion batteries (SIBs) and potassium-ion batteries (KIBs) have received much attention as next-generation energy storage systems owing to the abundance. Nevertheless, they face great challenges in the design of optimum electrode materials for practical applications. Herein, we prepared a unique two-dimensional structured composite consisting of N-doped carbon-coated CoSe2 nanocrystals and MXene nanosheets (CoSe2@NC/MX) for efficient electrochemical Na- and K-ion storage. In this strategy, a Co-based zeolitic imidazole framework (ZIF-67) was deposited on the surface of MXene nanosheets, and the subsequent selenization process resulted in the transformation of the ZIF-67 into CoSe2@NCs. The unique structure can shorten the transport pathways for electrons/ions and provide sufficient space to accommodate the volume change of the active materials. Furthermore, the N-doped carbon matrix and MXene can enhance the robustness of the electrode materials. Accordingly, the composites exhibited enhanced electrochemical performance in terms of cycle stability (317 mA h g(-1) after 200 cycles at 0.5 A g(-1)) and rate capability (343 mA h g(-1) at 7.0 A g(-1)) for SIBs. For KIBs, they exhibited a high reversible capacity of 358 mA h g(-1) at 0.5 A g(-1) after 100 cycles and 276 mA h g(-1) at a high rate of 2.0 A g(-1).

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