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초록
Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H-2 in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.
키워드
METAL-PROMOTED REACTIONS; BORON-NITROGEN BONDS; COUPLED-CAGE BORANE; AMINE-BORANE; HYDRIDES; AMINOBORANES; COMPLEXES; CARBORANE; NITRIDE; ROUTE
- 제목
- Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B-H Activation
- 저자
- Kim, Sung-Kwan; Han, Won-Sik; Kim, Tae-Jin; Kim, Tae-Young; Nam, Suk Woo; Mitoraj, Mariusz; Piekos, Lukasz; Michalak, Artur; Hwang, Son-Jong; Kang, Sang Ook
- 발행일
- 2010-07-28
- 유형
- Article
- 권
- 132
- 호
- 29
- 페이지
- 9954 ~ 9955