Organogermanium Nanowire Cathodes for Efficient Lithium-Oxygen Batteries

  • Lee, Gwang-Hee
  • Sung, Myeong-Chang
  • Kim, Yoon Seon
  • Ju, Bobae
  • Kim, Dong-Wan
Citations

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11
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12

초록

We report a technique for effectively neutralizing the generation of harmful superoxide species, the source of parasitic reactions, in lithium-oxygen batteries to generate stable substances. In organic electrolytes, organogermanium (Propa-germanium, Ge-132) nanowires can suppress solvated superoxide and induce strong surface-adsorption reaction due to their high anti-superoxide disproportionation activity. Resultantly, the effect of organogermanium nanowires mitigate toxic oxidative stress to stabilize organic electrolytes and promote good Li2O2 growth. These factors led to long duration of the electrolytes and impressive rechargeability of lithium-oxygen batteries.

키워드

organogermanium nanowiresanti-superoxide disproportionationLi2O2 growthsurface-adsorption reactionlithium-oxygen battery
제목
Organogermanium Nanowire Cathodes for Efficient Lithium-Oxygen Batteries
저자
Lee, Gwang-HeeSung, Myeong-ChangKim, Yoon SeonJu, BobaeKim, Dong-Wan
DOI
10.1021/acsnano.0c07262
발행일
2020-11-24
유형
Article
저널명
ACS Nano
14
11
페이지
15894 ~ 15903