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Solvent-assisted amine modification of graphite oxide for CO2 adsorption

Authors
Hong, S. -M.Lee, K. B.
Issue Date
2014
Publisher
ROYAL SOC CHEMISTRY
Citation
RSC ADVANCES, v.4, no.100, pp.56707 - 56712
Indexed
SCIE
SCOPUS
Journal Title
RSC ADVANCES
Volume
4
Number
100
Start Page
56707
End Page
56712
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/101234
DOI
10.1039/c4ra09314c
ISSN
2046-2069
Abstract
Amine-modified graphite oxides (GAs) for CO2 adsorption were prepared using 3-aminopropyltriethoxysilane. Graphite was first oxidized using highly concentrated acid, and then modified with the amine using a solvent-assisted method. Ethanol and water were used as the solvents, and the solvent effects were investigated. The morphological changes, functionalities, and compositions of the GAs were characterized by scanning electron microscopy, Fourier-transform infrared and X-ray photoelectron spectroscopies, and elemental analysis. The CO2 adsorption behavior was evaluated by thermogravimetric analysis at 30 degrees C under atmospheric pressure. The GA prepared in water (GA-W) had a higher CO2 adsorption uptake (1.64 mol kg(-1)) than did the GA prepared in ethanol (1.31 mol kg(-1)). The amine loading was predominantly influenced by the solvent, and water was an effective solvent for amine modification. GA-W also showed good regenerability in repeated adsorption-desorption cycles with high adsorption/desorption rates.
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공과대학 (화공생명공학과)
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