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Improvement of electrical properties in screen-printed crystalline silicon solar cells by contact treatment of the grid edge

Authors
Kim, SeongtakPark, SungeunKim, Young DoBoo, HyunpilKim, HyunhoBae, SoohyunPark, HyominTark, Sung JuKim, Donghwan
Issue Date
Nov-2013
Publisher
KOREAN INST METALS MATERIALS
Keywords
Si solar cells; screen-printing; electrical properties; scanning electron microscopy; Ag paste; HF treatment
Citation
METALS AND MATERIALS INTERNATIONAL, v.19, no.6, pp.1333 - 1338
Indexed
SCIE
SCOPUS
KCI
Journal Title
METALS AND MATERIALS INTERNATIONAL
Volume
19
Number
6
Start Page
1333
End Page
1338
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/101674
DOI
10.1007/s12540-013-6032-9
ISSN
1598-9623
Abstract
In this study, the influence of HF treatment of Ag pastes after a firing process was investigated. It was shown that the HF treatment can improve the fill factors and efficiencies of various cells including those with high initial specific contact resistances. SEM images showed that this improvement is due to the etching of the thin glass layer at the Ag-Si boundary, which exposes the Ag crystallites and colloids. These colloids electrically connect the bulk Ag to the Si through a direct contact, which reduces both the transfer length and the specific contact resistance. A model of the current path was proposed to explain the effect of HF treatment on the edge of the Ag grid.
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공과대학 (Department of Materials Science and Engineering)
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