Changes in the chemical composition of V2O5-loaded CVC-TiO2 materials with calcination temperatures for NH3-SCR of NOx
- Authors
- Cha, Woojoon; Park, Eunseuk; Chin, Sungmin; Yun, Seong-Taek; Jurng, Jongsoo
- Issue Date
- 10월-2013
- Publisher
- SPRINGER
- Keywords
- Chemical vapor condensation; V4+/5+; Formic acid; NOx
- Citation
- JOURNAL OF POROUS MATERIALS, v.20, no.5, pp.1069 - 1074
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF POROUS MATERIALS
- Volume
- 20
- Number
- 5
- Start Page
- 1069
- End Page
- 1074
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/101948
- DOI
- 10.1007/s10934-013-9688-0
- ISSN
- 1380-2224
- Abstract
- In this study, the aim was to evaluate the effect of calcinations temperature on the catalytic activity and chemical composition of V2O5/TiO2. We prepared V2O5-loaded CVC-TiO2 catalysts by a combination of chemical vapor condensation (CVC) and impregnation method at different calcination temperatures. These catalysts were analyzed for their ability to catalyze NH3-based selective catalytic reduction of NOx. Compared with V2O5 loaded P25-TiO2 (commercial). V2O5/CVC-TiO2 catalysts calcined above 200 A degrees C exhibited better performance towards NOx conversion than that by a commercial catalyst prepared using P25-TiO2 (calcined at 500 A degrees C). In addition, the NOx conversion rate obtained with the sample calcined at 500 A degrees C gave the best result (90 %) at a reaction temperature of 200 A degrees C. From the XPS results, we observed that the V4+/5+ ratio was well balanced when the V2O5 loaded CVC-TiO2 sample was calcined at 500 A(0)C.
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Collections - College of Science > Department of Earth and Environmental Sciences > 1. Journal Articles
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