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Mechanistic Insights into Oxidative Decomposition of exo-Tetrahydrodicyclopentadiene
- Authors
- Park, Sun Hee; Kwon, Cheong Hoon; Kim, Joongyeon; Han, Jeong Sik; Jeong, Byung Hun; Han, Hogyu; Kim, Sung Hyun
- Issue Date
- 8-Aug-2013
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF PHYSICAL CHEMISTRY C, v.117, no.31, pp.15933 - 15939
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF PHYSICAL CHEMISTRY C
- Volume
- 117
- Number
- 31
- Start Page
- 15933
- End Page
- 15939
- ISSN
- 1932-7447
- Abstract
- We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of O-2 at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O-2 as compared to in its absence. The O-2-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O-2-induced increase in the rate of C-10 product formation was higher than those of <C-10 and >C-10. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.
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Related Researcher
- Han, Ho gyu
- College of Science (College of Science)