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Synthesis of sterically-hindered 1,7-dicarba-closo-dodecarborane thiourea analogs

Authors
Choi, SeunghyunByun, Youngjoo
Issue Date
1-6월-2013
Publisher
ELSEVIER SCIENCE SA
Keywords
Carborane; Isothiocyanate; Thiourea; Conjugation
Citation
JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.733, pp.49 - 52
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume
733
Start Page
49
End Page
52
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/102994
DOI
10.1016/j.jorganchem.2013.03.003
ISSN
0022-328X
Abstract
We herein report the first successful synthesis of 1-thioisocyanato-1,7-dicarba-closo-dodecarborane, which afforded novel lipophilic thiourea analogs by reacting with weak and bulky nucleophilic amines including 1-adamantylamine, and m-carboranylamine, aniline, and 2-aminopyridine. Newly synthesized thiourea analogs were fully characterized by NMR, ESI-MS, and FTIR. (C) 2013 Elsevier B.V. All rights reserved.
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