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Hardness and Nitrogen Bonding Structure of A(x)Ti(1-x)N/CrN Multilayer Hard Coating

Authors
Seo, Jong-HyunYoon, Sang-WonChae, Keun-HwaPark, Jong-KeukSong, Jong-HanJayaram, VickramLee, Kon-BaeSeong, Tae-YeonKwon, HoonAhn, Jae-Pyoung
Issue Date
Feb-2012
Publisher
AMER SCIENTIFIC PUBLISHERS
Keywords
AlN/CrN; AlTiN/CrN; Multilayer Hard Coating; Crack Propagation; Broken Nitrogen Bond
Citation
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.12, no.2, pp.1581 - 1584
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume
12
Number
2
Start Page
1581
End Page
1584
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/106149
DOI
10.1166/jnn.2012.4700
ISSN
1533-4880
Abstract
AlxTi1-xN/CrN multilayer coatings were fabricated by magnetron sputtering and those hardness variations were studied by observing the crack propagation and measuring the chemical bonding state of nitrides by Ti addition. While AlN/CrN multilayer shown stair-like crack propagation, AlxTi1-xN/CrN multilayer illustrated straight crack propagation. Most interestingly, Ti addition induced more broken nitrogen bonds in the nitride multilayers, leading to the reduction of hardness. However, the hardness of Al0.25Ti0.75N/CrN multilayer, having high Ti contents, increased by the formation of many Ti-N bond again instead of Al-N bond. From these results, we found that linear crack propagation behavior was dominated by broken nitrogen bonds in the AlxT1-xN/CrN multilayer coatings.
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College of Engineering (Department of Materials Science and Engineering)
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