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Morphological diversity of Mn(III) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

Authors
Lee, Kyung YeonLee, Young SunKim, SundolHoang Mai HaBae, Sang-EunHuh, SeongJang, Ho GyeomLee, Suk Joong
Issue Date
2013
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.15, no.45, pp.9360 - 9363
Indexed
SCIE
SCOPUS
Journal Title
CRYSTENGCOMM
Volume
15
Number
45
Start Page
9360
End Page
9363
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/106503
DOI
10.1039/c3ce41072b
ISSN
1466-8033
Abstract
A series of narrowly dispersed nano-and microsized CPAs has been prepared from a (porphyrin)Mn(III) biscarboxylic acid and Co(OAc)(2). The morphologies have been diversified from amorphous spheres to crystalline cubes by varying reaction periods. In addition, their heterogeneous catalytic olefin oxidations are successfully demonstrated.
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