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High yield synthesis of catalytically active five-fold twinned Pt nanorods from a surfactant-ligated precursor

Authors
Yoon, JisunNguyen Tien KhiKim, HeonjoKim, ByeongyoonBaik, HionsuckBack, SeunghoonLee, SangminLee, Sang-WonKwon, Seong JungLee, Kwangyeol
Issue Date
2013
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.49, no.6, pp.573 - 575
Indexed
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
49
Number
6
Start Page
573
End Page
575
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/106587
DOI
10.1039/c2cc36905b
ISSN
1359-7345
Abstract
The CO-assisted thermal decomposition of a new, surfactant-ligated Pt precursor, [Pt(acac)(NHR)](n) (n = 2, 3; R = C18H37), gives structurally uniform five-fold twinned Pt nanorods. The Pt nanorods, mostly covered by {100} facets, exhibit much enhanced electrocatalytic activity over {100} faceted Pt nanocubes, indicating the superior catalytic performance due to the presence of the reactive twinning interface.
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