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KF and CsF Recognition and Extraction by a Calix[4]crown-5 Strapped Calix[4]pyrrole Multitopic Receptor

Authors
Kim, Sung KukLynch, Vincent M.Young, Neil J.Hay, Benjamin P.Lee, Chang-HeeKim, Jong SeungMoyer, Bruce A.Sessler, Jonathan L.
Issue Date
26-12월-2012
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.134, no.51, pp.20837 - 20843
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume
134
Number
51
Start Page
20837
End Page
20843
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/106635
DOI
10.1021/ja310673p
ISSN
0002-7863
Abstract
On the basis of H-1 NMR spectroscopic analyses and single crystal X-ray crystal structural data, the ion-pair receptor 1, bearing a calix[4]pyrrole for anion binding and calix[4]arene crown-5 for cation recognition, was found to act as a receptor for both CsF and KF ion-pairs. Both substrates are bound strongly but via different binding modes and with different complexation dynamics. Specifically, exposure to KF in 10% CD3OD in CDCl3 leads first to complexation of the K+ cation by the calix[4]arene crown-5 moiety. As the relative concentration of KF increases, then the calix[4]pyrrole subunit binds the F- anion. Once bound, the K+ cation and the F- anion give rise to a stable 1:1 ion-pair complex that generally precipitates from solution. In contrast to what is seen with KF, the CsF ion-pair interacts with receptor 1 in two different modes in 10% CD3OD in CDCl3. In the first of these, the Cs+ cation interacts with the calix[4]arene crown-5 ring weakly. In the second interaction mode, which is thermodynamically more stable, the Cs+ cation and the counteranion, F-, are simultaneously bound to the receptor framework. Further proof that system 1 acts as a viable ion-pair receptor came from the finding that receptor 1 could extract KF from an aqueous phase into nitrobenzene, overcoming the high hydration energies of the K+ and F- ions. It was more effective in this regard than a 1:1 mixture of the constituent cation and anion receptors (4 and 5).
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