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'Cleft-form' electrochemical anion chemosensor with amide and triazole donor groups
- Issue Date
- 12-9월-2012
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Ferrocene; ' Cleft-form' receptor; Anions sensing
- Citation
- TETRAHEDRON LETTERS, v.53, no.37, pp.4917 - 4920
- Indexed
- SCIE
SCOPUS
- Journal Title
- TETRAHEDRON LETTERS
- Volume
- 53
- Number
- 37
- Start Page
- 4917
- End Page
- 4920
- ISSN
- 0040-4039
- Abstract
- A novel 'cleft-form' electrochemical anion receptor bearing amide and triazole donor groups, 1, has been synthesized and characterized. Among various anions, 1 shows a significant anodic shift response for H2PO4- and F-, with its multiple N-H center dot center dot center dot anion and C-H center dot center dot center dot anion interactions, which is supported by theoretical calculation and NMR titration results. (C) 2012 Elsevier Ltd. All rights reserved.
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