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'Cleft-form' electrochemical anion chemosensor with amide and triazole donor groups

Authors
Cao, Qian-YongPradhan, TuhinLee, Min HeeChoi, Dong HoonKim, Jong Seung
Issue Date
12-9월-2012
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Ferrocene; ' Cleft-form' receptor; Anions sensing
Citation
TETRAHEDRON LETTERS, v.53, no.37, pp.4917 - 4920
Indexed
SCIE
SCOPUS
Journal Title
TETRAHEDRON LETTERS
Volume
53
Number
37
Start Page
4917
End Page
4920
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/107465
DOI
10.1016/j.tetlet.2012.06.118
ISSN
0040-4039
Abstract
A novel 'cleft-form' electrochemical anion receptor bearing amide and triazole donor groups, 1, has been synthesized and characterized. Among various anions, 1 shows a significant anodic shift response for H2PO4- and F-, with its multiple N-H center dot center dot center dot anion and C-H center dot center dot center dot anion interactions, which is supported by theoretical calculation and NMR titration results. (C) 2012 Elsevier Ltd. All rights reserved.
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