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Organic donor-sigma-acceptor molecules based-on 5,5 '-(9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2-hexylthiophene)

Authors
Shin, JicheolLee, Tae WanKang, Nam SuKim, Kyung HwanHong, Jae-MinChoi, Dong Hoon
Issue Date
Sep-2012
Publisher
ELSEVIER SCIENCE SA
Keywords
Conjugated molecules; Anthracene; PCBM; Donor-sigma-acceptor; Semiconductor; Photovoltaic cell
Citation
SYNTHETIC METALS, v.162, no.15-16, pp.1335 - 1342
Indexed
SCIE
SCOPUS
Journal Title
SYNTHETIC METALS
Volume
162
Number
15-16
Start Page
1335
End Page
1342
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/107560
DOI
10.1016/j.synthmet.2012.05.010
ISSN
0379-6779
Abstract
New donor-sigma-acceptor (D-sigma-A) molecules of (HAT)-n(PCBM) (where n=1 and 2; PCBM refers to [6,6]-phenyl C61-butyric acid methyl ester and HAT refers to 5,5'-(9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2-hexylthiophene)) were successfully synthesized for studying the intermolecular association behavior and their possible applications of these molecules to photovoltaic (PV) devices. In PV devices, (HAT)-n(PCBM) gave a reasonably high power conversion efficiency (PCE) of 0.18-0.44% with an open circuit voltage (V-oc) ranging from 0.42 to 0.51 V without adding extra amount of PCBM. (C) 2012 Elsevier B.V. All rights reserved.
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