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Functionalized organic dyes containing a phenanthroimidazole donor for dye-sensitized solar cell applications

Authors
Lee, WoochulYang, YounaCho, NaraKo, JaejungHong, Jong-In
Issue Date
8-7월-2012
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Dye-sensitized solar cells (DSSCs); Organic dyes; Phenanthroimidazole; Squaraine dye
Citation
TETRAHEDRON, v.68, no.27-28, pp.5590 - 5598
Indexed
SCIE
SCOPUS
Journal Title
TETRAHEDRON
Volume
68
Number
27-28
Start Page
5590
End Page
5598
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/107941
DOI
10.1016/j.tet.2012.04.074
ISSN
0040-4020
Abstract
Five functionalized organic dyes (H6-10) containing a phenanthroimidazole unit as an electron donor were synthesized and characterized for use in dye-sensitized solar cell (DSSC) applications. Under standard global AM 1.5 solar conditions, the DSSCs based on dye H6 displayed the best performance, with an incident photon-to-current conversion efficiency (IPCE) exceeding 70% at wavelengths of 400-530 nm, a short-circuit photocurrent density of 10.98 mA cm(-2), an open-circuit voltage of 0.68 V. a fill factor of 0.69, and an overall conversion efficiency of 5.12%. This efficiency is similar to 94% of that for JK2 cells (5.46%) and similar to 72% of that for N719 cells (7.07%) under the same conditions. (c) 2012 Elsevier Ltd. All rights reserved.
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