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Cyanide-bridged (WMnIII)-Mn-V single-chain magnet based on an octacoordinate [W(CN)(6)(phen)](-) anion
- Authors
- Lee, JinWuk; Lim, KwangSoo; Yoon, JungHee; Ryu, DaeWon; Koo, BongHo; Koh, EuiKwan; Hong, ChangSeop
- Issue Date
- 6월-2012
- Publisher
- SCIENCE PRESS
- Keywords
- tungsten; manganese; cyanide; crystal structure; single-chain magnet
- Citation
- SCIENCE CHINA-CHEMISTRY, v.55, no.6, pp.1012 - 1017
- Indexed
- SCIE
SCOPUS
- Journal Title
- SCIENCE CHINA-CHEMISTRY
- Volume
- 55
- Number
- 6
- Start Page
- 1012
- End Page
- 1017
- ISSN
- 1674-7291
- Abstract
- Reaction of unique [W(CN)(6)(phen)(-) with a magnetically anisotropic Mn Schiff base yielded a W-V(5d)-Mn-III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.
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