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Tip-Enhanced Raman Scattering with a Nanoparticle-Functionalized Probe

Authors
Park, Chan-GyuKim, Ju-YoungLee, EunbyoulChoi, Han-KyuPark, Won-HwaKim, JinwookKim, Zee Hwan
Issue Date
20-5월-2012
Publisher
KOREAN CHEMICAL SOC
Keywords
Plasmons; Nanoparticles; Raman scattering
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.33, no.5, pp.1748 - 1752
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
33
Number
5
Start Page
1748
End Page
1752
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/108409
DOI
10.5012/bkcs.2012.33.5.1748
ISSN
0253-2964
Abstract
We carried out the tip-enhanced Raman scattering (TERS) with a tip that is functionalized with a Au-nanoparticle (AuNP, with a diameter of 250 nm). The AuNP tip is fabricated by a direct mechanical pickup of a AuNP from a flat substrate, and the TERS signal from the AuNP tip - organic monolayer - Au thin film (thickness of 10 nm) is recorded. We find that such a AuNP-tip interacting with a thin film routinely yields signal enhancement larger than similar to 10(4), which is sufficient not only for local (with detection area of similar to 200 nm(2)) Raman spectroscopy, but also the nanometric imaging of organic monolayers within a reasonable acquisition time (similar to 20 minutes/image).
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