Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites
DC Field | Value | Language |
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dc.contributor.author | Kim, Joongyeon | - |
dc.contributor.author | Park, Sun Hee | - |
dc.contributor.author | Chun, Byung-Hee | - |
dc.contributor.author | Jeong, Byung Hun | - |
dc.contributor.author | Han, Jeong Sik | - |
dc.contributor.author | Kim, Sung Hyun | - |
dc.date.accessioned | 2021-09-06T19:46:03Z | - |
dc.date.available | 2021-09-06T19:46:03Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2012-05-20 | - |
dc.identifier.issn | 0920-5861 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/108413 | - |
dc.description.abstract | Endothermic reactions of methylcyclohexane (MCH) with zeolites were investigated in a batch reactor to increase the heats of reaction. Conversion and product distribution affected the heat of reaction. The heat of reaction with HZSM-5, which led to the formation of low-molecular-weight hydrocarbon products, was larger than the heats of reaction with other zeolites. To improve the heat of reaction with HZSM-5, Pt/HZSM-5 (1 wt.% Pt) was used in endothermic reactions. In endothermic reactions with Pt/HZSM-5, the heats of reaction increased, and there was a high yield of olefins, which were formed by dehydrogenation of paraffin on metal sites. A high conversion and high yield of low-molecular-weight hydrocarbons and olefins led to an increase in the heat of reaction. (C) 2011 Published by Elsevier B.V. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.subject | HYDROGEN | - |
dc.subject | CYCLOALKANES | - |
dc.subject | MECHANISMS | - |
dc.subject | CRACKING | - |
dc.subject | CATALYST | - |
dc.subject | FUELS | - |
dc.title | Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Chun, Byung-Hee | - |
dc.contributor.affiliatedAuthor | Kim, Sung Hyun | - |
dc.identifier.doi | 10.1016/j.cattod.2011.09.020 | - |
dc.identifier.wosid | 000303109100007 | - |
dc.identifier.bibliographicCitation | CATALYSIS TODAY, v.185, no.1, pp.47 - 53 | - |
dc.relation.isPartOf | CATALYSIS TODAY | - |
dc.citation.title | CATALYSIS TODAY | - |
dc.citation.volume | 185 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 47 | - |
dc.citation.endPage | 53 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Proceedings Paper | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | HYDROGEN | - |
dc.subject.keywordPlus | CYCLOALKANES | - |
dc.subject.keywordPlus | MECHANISMS | - |
dc.subject.keywordPlus | CRACKING | - |
dc.subject.keywordPlus | CATALYST | - |
dc.subject.keywordPlus | FUELS | - |
dc.subject.keywordAuthor | Heat of reaction | - |
dc.subject.keywordAuthor | Methylcyclohexane | - |
dc.subject.keywordAuthor | Zeolites | - |
dc.subject.keywordAuthor | Low-molecular-weight hydrocarbons | - |
dc.subject.keywordAuthor | Olefins | - |
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