Detailed Information

Cited 0 time in webofscience Cited 0 time in scopus
Metadata Downloads

Improvement of the heats of reaction in endothermic reactions of methylcyclohexane with zeolites

Authors
Kim, JoongyeonPark, Sun HeeChun, Byung-HeeJeong, Byung HunHan, Jeong SikKim, Sung Hyun
Issue Date
20-5월-2012
Publisher
ELSEVIER SCIENCE BV
Keywords
Heat of reaction; Methylcyclohexane; Zeolites; Low-molecular-weight hydrocarbons; Olefins
Citation
CATALYSIS TODAY, v.185, no.1, pp.47 - 53
Indexed
SCIE
SCOPUS
Journal Title
CATALYSIS TODAY
Volume
185
Number
1
Start Page
47
End Page
53
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/108413
DOI
10.1016/j.cattod.2011.09.020
ISSN
0920-5861
Abstract
Endothermic reactions of methylcyclohexane (MCH) with zeolites were investigated in a batch reactor to increase the heats of reaction. Conversion and product distribution affected the heat of reaction. The heat of reaction with HZSM-5, which led to the formation of low-molecular-weight hydrocarbon products, was larger than the heats of reaction with other zeolites. To improve the heat of reaction with HZSM-5, Pt/HZSM-5 (1 wt.% Pt) was used in endothermic reactions. In endothermic reactions with Pt/HZSM-5, the heats of reaction increased, and there was a high yield of olefins, which were formed by dehydrogenation of paraffin on metal sites. A high conversion and high yield of low-molecular-weight hydrocarbons and olefins led to an increase in the heat of reaction. (C) 2011 Published by Elsevier B.V.
Files in This Item
There are no files associated with this item.
Appears in
Collections
College of Engineering > Department of Chemical and Biological Engineering > 1. Journal Articles

qrcode

Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.

Altmetrics

Total Views & Downloads

BROWSE