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Ga Ordering and Electrical Conductivity in Nanotwin and Superlattice-Structured Ga-Doped ZnO

Authors
Yoon, Sang-WonSeo, Jong-HyunSeong, Tae-YeonYu, Tae HwanYou, Yil HwanLee, Kon BaeKwon, HoonAhn, Jae-Pyoung
Issue Date
Mar-2012
Publisher
AMER CHEMICAL SOC
Citation
CRYSTAL GROWTH & DESIGN, v.12, no.3, pp.1167 - 1172
Indexed
SCIE
SCOPUS
Journal Title
CRYSTAL GROWTH & DESIGN
Volume
12
Number
3
Start Page
1167
End Page
1172
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/108999
DOI
10.1021/cg2010908
ISSN
1528-7483
Abstract
We have investigated the Ga-ordering controlled by structural changes from nanotwin to superlattice in Ga-doped ZnO (GZO) targets for transparent conductive oxides (TCOs) and discussed the distribution effect of Ga atoms on electrical conductivities of GZOs. The nanotwin and superlattice structures were preferentially formed by Ga-doping and sintering at high temperature. The relative fraction of nanotwin increased above transition concentration (TC approximate to 5.6 wt % Ga). Here, we found that Ga atoms at nanotwin are distributed as clustered and disordered states, while they are completely ordered in superlattice. Ultimately, the superlattice leads to high electrical conductivity in GZOs rather than the nanotwin.
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