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FACILE AND EFFICIENT METHOD FOR THE DEBROMINATION OF vic-DIBROMIDES TO ALKENES WITH BiCl3/Ga SYSTEM
- Authors
- Yoo, Byung Woo; Kim, Seo Hee; Park, Young Kwang
- Issue Date
- 2012
- Publisher
- TAYLOR & FRANCIS INC
- Keywords
- Alkene; bismuth; debromination; gallium
- Citation
- SYNTHETIC COMMUNICATIONS, v.42, no.11, pp.1632 - 1636
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNTHETIC COMMUNICATIONS
- Volume
- 42
- Number
- 11
- Start Page
- 1632
- End Page
- 1636
- ISSN
- 0039-7911
- Abstract
- BiCl3/Ga was found to be a mild, efficient, and chemoselective system for the debromination of a series of functionally and structurally various vic-dibromides. A broad range of functional groups (ester, carboxy, aldehyde, methoxy, chloro, and ketone) was tolerated under the reaction conditions and only trans olefins were obtained in good yields.
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