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Cyanide-Bridged (WMnIII)-Mn-v Single-Chain Magnet with Isolated Mn-III Moieties Exhibiting Two Types of Relaxation Dynamics
- Authors
- Yoon, Jung Hee; Lee, Jin Wuk; Ryu, Dae Won; Choi, Sang Yup; Yoon, Sung Won; Suh, Byoung Jin; Koh, Eui Kwan; Kim, Hyoung Chan; Hong, Chang Seop
- Issue Date
- 21-Nov-2011
- Publisher
- AMER CHEMICAL SOC
- Citation
- INORGANIC CHEMISTRY, v.50, no.22, pp.11306 - 11308
- Indexed
- SCIE
SCOPUS
- Journal Title
- INORGANIC CHEMISTRY
- Volume
- 50
- Number
- 22
- Start Page
- 11306
- End Page
- 11308
- ISSN
- 0020-1669
- Abstract
- A 5d-3d bimetallic compound was prepared by self-assembling [W(CN)(8)](3-) and the Mn-III Schiff bases. This neutral complex consists of cyanide-linked anionic chains and isolated Mn-III Schiff base cations. We demonstrate that two types of relaxation processes are involved in the system; the low-T dynamics may come from magnetic domain dynamics and the high-T relaxation stems from the anionic chain, revealing single-chain magnet character.
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