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(1,2-Dicarba-closo-dodecaboranyl)trimethylmethanaminium iodide
- Authors
- Lee, Jong-Dae; Han, Won-Sik; Suh, Il-Hwan; Kang, Sang Ook
- Issue Date
- 8월-2011
- Publisher
- WILEY-BLACKWELL
- Keywords
- data-to-parameter ratio = 23.9; mean σ(CC) = 0.004 Å; R factor = 0.031; single-crystal X-ray study; T = 293 K; wR factor = 0.076
- Citation
- ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.67, pp.O2148 - U1533
- Indexed
- SCIE
SCOPUS
- Volume
- 67
- Start Page
- O2148
- End Page
- U1533
- ISSN
- 1600-5368
- Abstract
- The title compound, [1-(CH3)(3)NCH2-1,2-C2B10H11](+)center dot I- or C6H22B10N+center dot I-, was obtained by the reaction of (1,2-dicarba-closo-dodecaboranyl) dimethylmethanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboranyl)tetramethylammonium cations. The bond lengths and angles in the carborane cage are within normal ranges, but the N-C-methylene-C-cage angle is very large [120.2 (2)degrees] because of repulsion between the carborane and tetramethylammonium units. In the crystal, ions are linked through C-H center dot center dot center dot I hydrogen bonds.
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Collections - Graduate School > Department of Advanced Materials Chemistry > 1. Journal Articles
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