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Low Temperature Sintering and Microwave Dielectric Properties of B2O3-added LiAlSiO4 Ceramics

Authors
Kweon, Sang-HyoJoung, Mi-RiKim, Jin-SeongKim, Bo-YunNahm, SahnPaik, Jong-HooKim, Young-SikSung, Tae-Hyun
Issue Date
7월-2011
Publisher
WILEY-BLACKWELL
Citation
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, v.94, no.7, pp.1995 - 1998
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume
94
Number
7
Start Page
1995
End Page
1998
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/112183
DOI
10.1111/j.1551-2916.2011.04619.x
ISSN
0002-7820
Abstract
The sintering temperature of the LiAlSiO4(LAS) ceramics, which exhibited the microwave dielectric properties of epsilon(r) = 4.8, Q x f = 36 000GHz, and tau(f)=8.0 ppm/degrees C, decreased below 960 degrees C when B2O3 was added. The B2O3-related liquid phase was formed and assisted the densification of the LAS ceramics at low temperatures. The average grain size of the specimen sintered at 950 degrees C increased with the addition of B2O3 but decreased when B2O3 exceeded 12.0 mol%, probably due to the presence of a large amount of liquid phase. The LAS ceramics containing 12.0 mol% of B2O3 sintered at 950 degrees C exhibited the excellent microwave dielectric properties of epsilon(r) = 5.3, Qxf = 212 000GHz and tau(f) = -7.7 ppm/degrees C.
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