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Enzymatic coproduction of biodiesel and glycerol carbonate from soybean oil and dimethyl carbonate

Authors
Seong, Pil-JeJeon, Byoung WookLee, MyungguCho, Dae HaengKim, Duk-KiJung, Kwang S.Kim, Seung WookHan, Sung OkKim, Yong HwanPark, Chulhwan
Issue Date
6-5월-2011
Publisher
ELSEVIER SCIENCE INC
Keywords
Biodiesel; Glycerol carbonate; Dimethyl carbonate; tert-Butanol; Coproduction
Citation
ENZYME AND MICROBIAL TECHNOLOGY, v.48, no.6-7, pp.505 - 509
Indexed
SCIE
SCOPUS
Journal Title
ENZYME AND MICROBIAL TECHNOLOGY
Volume
48
Number
6-7
Start Page
505
End Page
509
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/112465
DOI
10.1016/j.enzmictec.2011.02.009
ISSN
0141-0229
Abstract
The enzymatic coproduction of biodiesel and glycerol carbonate by the transesterification of soybean oil was studied using lipase as catalyst in organic solvent. To produce biodiesel and glycerol carbonate simultaneously, experiments were designed sequentially. Enzyme screening, the molar ratio of dimethyl carbonate (DMC) to soybean oil, reaction temperature and solvent effects were investigated. The results of enzyme screening, at 100 g/L Novozym 435 (immobilized Candida antarctica lipase B), biodiesel and glycerol carbonate showed conversions of 58.7% and 50.7%, respectively. The optimal conditions were 60 degrees C, 100 g/L Novozym 435, 6.0:1 molar ratio with tert-butanol as solvent: 84.9% biodiesel and 92.0% glycerol carbonate production was achieved. (C) 2011 Elsevier Inc. All rights reserved.
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