Enzymatic coproduction of biodiesel and glycerol carbonate from soybean oil and dimethyl carbonate
- Authors
- Seong, Pil-Je; Jeon, Byoung Wook; Lee, Myunggu; Cho, Dae Haeng; Kim, Duk-Ki; Jung, Kwang S.; Kim, Seung Wook; Han, Sung Ok; Kim, Yong Hwan; Park, Chulhwan
- Issue Date
- 6-5월-2011
- Publisher
- ELSEVIER SCIENCE INC
- Keywords
- Biodiesel; Glycerol carbonate; Dimethyl carbonate; tert-Butanol; Coproduction
- Citation
- ENZYME AND MICROBIAL TECHNOLOGY, v.48, no.6-7, pp.505 - 509
- Indexed
- SCIE
SCOPUS
- Journal Title
- ENZYME AND MICROBIAL TECHNOLOGY
- Volume
- 48
- Number
- 6-7
- Start Page
- 505
- End Page
- 509
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/112465
- DOI
- 10.1016/j.enzmictec.2011.02.009
- ISSN
- 0141-0229
- Abstract
- The enzymatic coproduction of biodiesel and glycerol carbonate by the transesterification of soybean oil was studied using lipase as catalyst in organic solvent. To produce biodiesel and glycerol carbonate simultaneously, experiments were designed sequentially. Enzyme screening, the molar ratio of dimethyl carbonate (DMC) to soybean oil, reaction temperature and solvent effects were investigated. The results of enzyme screening, at 100 g/L Novozym 435 (immobilized Candida antarctica lipase B), biodiesel and glycerol carbonate showed conversions of 58.7% and 50.7%, respectively. The optimal conditions were 60 degrees C, 100 g/L Novozym 435, 6.0:1 molar ratio with tert-butanol as solvent: 84.9% biodiesel and 92.0% glycerol carbonate production was achieved. (C) 2011 Elsevier Inc. All rights reserved.
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Collections - College of Engineering > Department of Chemical and Biological Engineering > 1. Journal Articles
- Graduate School > Department of Biotechnology > 1. Journal Articles
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