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Simple Synthetic Manipulation Allowing for Morphological Diversity of Porphyrin-Based Microcrystals

Authors
Lee, Jun HoRyu, Eui-HyunKim, SungtaeLee, Suk Joong
Issue Date
20-2월-2011
Publisher
WILEY-V C H VERLAG GMBH
Keywords
Amphiphilic; Porphyrin; Building block; Nanocrystalline; CTAB
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.32, no.2, pp.609 - 612
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
32
Number
2
Start Page
609
End Page
612
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/113052
DOI
10.5012/bkcs.2011.32.2.609
ISSN
0253-2964
Abstract
Amphiphilic (porphyrin)Sn(OH)(2) molecular building block can directly translate into well-defined solid-state microcrystalline structures. The crystalline diamond plates are obtained from ethanol and crystalline square plates are grown from methanol solution. With a simple synthetic manipulation during the microcrystal growth, the morphologies can be controlled by adopting different molecular packing. Consequently, morphologies of microcrystals have been diversified. Furthermore, the macroscopic crystals were obtained in the presence of cetyltrimethylammonium bromide (CTAB).
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