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Metal impurities behaviors of silicon in the fractional melting process

Authors
Lee, WoosoonKim, JoonsooJang, Bo-yunAhn, YoungsooLee, HeonYoon, Wooyoung
Issue Date
Jan-2011
Publisher
ELSEVIER SCIENCE BV
Keywords
Si refining; Fractional melting; Metal impurity
Citation
SOLAR ENERGY MATERIALS AND SOLAR CELLS, v.95, no.1, pp.59 - 62
Indexed
SCIE
SCOPUS
Journal Title
SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume
95
Number
1
Start Page
59
End Page
62
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/113423
DOI
10.1016/j.solmat.2010.02.014
ISSN
0927-0248
Abstract
The photovoltaic (PV) rapid growth suffers the severe shortage of silicon. The metallurgical route to solar grade (SoG) silicon is the alternative solution. One of the methods suggested the fractional melting process. Because the metal impurities in the metallurgical grade (MG) silicon such as Fe, Al, Ti and Cu deteriorate the efficiency of the solar cell seriously, it is important to remove those metal elements from MG-Si to upgrade the silicon. The refining behaviors of the metal impurities, however, do not equal in FM process. Cu and Al behaviors in the Si during FM process are studied using SEM, EPMA and ICP-AES. The diffusion coefficient and the grain boundary (GB) enrichment behaviors of the elements are rationalized to cause the difference. (C) 2010 Elsevier B.V. All rights reserved.
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