High-temperature hydrodechlorination of ozone-depleting chlorodifluoromethane (HCFC-22) on supported Pd and Ni catalysts
- Authors
- Ha, Jeong-Myeong; Kim, Daewoo; Kim, Jaehoon; Ahn, Byoung Sung; Kim, Yunje; Kang, Jeong Won
- Issue Date
- 2011
- Publisher
- TAYLOR & FRANCIS INC
- Keywords
- HCFC-22; HFC-23; HFC-32; nickel; palladium; catalysis; hydrodechlorination
- Citation
- JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, v.46, no.9, pp.989 - 996
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING
- Volume
- 46
- Number
- 9
- Start Page
- 989
- End Page
- 996
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/114881
- DOI
- 10.1080/10934529.2011.586262
- ISSN
- 1093-4529
- Abstract
- The hydrodechlorination of chlorodifluoromethane (HCFC-22) was performed by a catalytic reaction and noncatalytic thermal decomposition at high temperatures of 400-800 degrees C. After 47 h of time-on-stream on a supported palladium (Pd) catalyst, the gas-phase composition of difluoromethane (HFC-32) is 41.0%, with 4.9% of the HCFC-22 remaining, indicating the conversion of up to 95.1% of HCFC-22. The supported nickel catalyst's deactivation is significant as it exhibits the low conversion of HCFC-22 under the same reaction conditions. The deactivation of the catalyst is caused by the polymerization of adsorbed methyl radicals, which competes with the formation of HFC-32. With concentrated reactants at high reaction temperatures, there was an increase in the catalytic activity; however, unwanted tar, methane, and trifluoromethane (HFC-23) by-products are also produced. The use of catalyst suppresses the formation of these by-products. Considering the compositions of the products of the catalytic and noncatalytic reactions, we demonstrate that the use of the supported-metal catalysts and hydrogen flow suppresses tar formation and lowers the required reaction temperature.
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Collections - Graduate School of Energy and Environment (KU-KIST GREEN SCHOOL) > Department of Energy and Environment > 1. Journal Articles
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