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Spin crossover in the cyanide-bridged (MoMnIII)-Mn-V single-chain magnet containing Fe-II cations
- Authors
- Yoon, Jung Hee; Ryu, Dae Won; Choi, Sang Yup; Kim, Hyoung Chan; Koh, Eui Kwan; Tao, Jun; Hong, Chang Seop
- Issue Date
- 2011
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.47, no.37, pp.10416 - 10418
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 47
- Number
- 37
- Start Page
- 10416
- End Page
- 10418
- ISSN
- 1359-7345
- Abstract
- A 1D (MoMnIII)-Mn-V chain compound balanced by {Fe[ HC(3,5-Me(2)pz)(3)](2)}(2+) dications was prepared. This complex displays a typical single-chain magnet character associated with the (MoMnIII)-Mn-V chain and a spin crossover phenomenon arising from cationic Fe(II) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.
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