Ultrathin, Organic, Semiconductor/Polymer Blends by Scanning Corona-Discharge Coating for High-Performance Organic Thin-Film Transistors
- Authors
- Jung, Hee Joon; Shin, Yu Jin; Park, Youn Jung; Yoon, Sung Cheol; Choi, Dong Hoon; Park, Cheolmin
- Issue Date
- 9-Sep-2010
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ADVANCED FUNCTIONAL MATERIALS, v.20, no.17, pp.2903 - 2910
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED FUNCTIONAL MATERIALS
- Volume
- 20
- Number
- 17
- Start Page
- 2903
- End Page
- 2910
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/115690
- DOI
- 10.1002/adfm.201000032
- ISSN
- 1616-301X
- Abstract
- A new thin-film coating process, scanning corona-discharge coating (SCDC), to fabricate ultrathin tri-isopropylsilylethynyl pentacene (TIPS-PEN)/amorphous-polymer blend layers suitable for high-performance, bottom-gate, organic thin-film transistors (OTFTs) is described. The method is based on utilizing the electrodynamic flow of gas molecules that are corona-discharged at a sharp metallic tip under a high voltage and subsequently directed towards a bottom electrode. With the static movement of the bottom electrode, on which a blend solution of TIPS-PEN and an amorphous polymer is deposited, SCDC provides an efficient route to produce uniform blend films with thicknesses of less than one hundred nanometers, in which the TIPS-PEN and the amorphous polymer are vertically phase-separated into a bilayered structure with a single-crystalline nature of the TIPS-PEN. A bottom-gate field-effect transistor with a blend layer of TIPS-PEN/polystyrene (PS) (90/10 wt%) operated at ambient conditions, for example, indeed exhibits a highly reliable device performance with a field-effect mobility of approximately 0.23 cm(2) V(-1) s(-1) : two orders of magnitude greater than that of a spin-coated blend film. SCDC also turns out to be applicable to other amorphous polymers, such as poly(alpha-methyl styrene) and poly(methyl methacrylate) and, readily combined with the conventional transfer-printing technique, gives rise to micropatterned arrays of TIPS-PEN/polymer films.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Science > Department of Chemistry > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholar.korea.ac.kr/handle/2021.sw.korea/115690)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.