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Naphthalimide Modified Rhodamine Derivative: Ratiometric and Selective Fluorescent Sensor for Cu2+ Based on Two Different Approaches

Authors
Zhang, Jun FengZhou, YingYoon, JuyoungKim, YoungmeeKim, Sung JinKim, Jong Seung
Issue Date
3-9월-2010
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.12, no.17, pp.3852 - 3855
Indexed
SCIE
SCOPUS
Journal Title
ORGANIC LETTERS
Volume
12
Number
17
Start Page
3852
End Page
3855
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/115697
DOI
10.1021/ol101535s
ISSN
1523-7060
Abstract
A new rhodamine-based derivative bearing a 1,8-naphthalimide group (1) was synthesized as a dual-mode Cu2+-selective sensor via the rhodamine ring-opening approach and ratiometric displacement. A colorimetric and "off on" signal for Cu2+ through rhodamine ring opening in 1 and ratiometric fluorescent signal output when Cu2+ displaces the bound Zn2+ in the 1-Zn2+ complex can be observed.
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