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Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B-H Activation
- Authors
- Kim, Sung-Kwan; Han, Won-Sik; Kim, Tae-Jin; Kim, Tae-Young; Nam, Suk Woo; Mitoraj, Mariusz; Piekos, Lukasz; Michalak, Artur; Hwang, Son-Jong; Kang, Sang Ook
- Issue Date
- 28-Jul-2010
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.29, pp.9954 - 9955
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 132
- Number
- 29
- Start Page
- 9954
- End Page
- 9955
- ISSN
- 0002-7863
- Abstract
- Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H-2 in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.
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