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A study on the characteristics of CO oxidation at room temperature by metallic Pt

Authors
Seo, Phil WonChoi, Hyun JinHong, Sul InHong, Sung Chang
Issue Date
15-Jun-2010
Publisher
ELSEVIER
Keywords
Carbon monoxide; Pt/TiO2; Room temperature; Non-stoichiometric
Citation
JOURNAL OF HAZARDOUS MATERIALS, v.178, no.1-3, pp.917 - 925
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF HAZARDOUS MATERIALS
Volume
178
Number
1-3
Start Page
917
End Page
925
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/116234
DOI
10.1016/j.jhazmat.2010.02.025
ISSN
0304-3894
Abstract
Various experiments and analysis were conducted in order to manufacture a catalyst that could very efficiently oxidize carbon monoxide at room temperature and also to identify the relevant factors influencing the oxidation reaction. Pt/TiO2 catalyst can increase the oxidizing capability of CO at low temperature and room temperature by reduction. In FT-IR experiments, the catalyst that displayed excellent activity was capable of efficiently oxidizing CO to CO2 using atmospheric oxygen. Based on the results of XPS analysis, we found that the reduced catalyst changed the platinum's oxidation value to Pt+2 and Pt+0, Through the O-2-reoxidation experiments, the catalyst, which consisted of non-stoichiometric platinum oxidized species, displayed an excellent ability to accept oxygen. In this study, the Pt/TiO2 catalyst was able to very efficiently oxidize CO at low temperature and room temperature even with a minute quantity of platinum. (C) 2010 Elsevier B.V. All rights reserved.
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