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The synthesis and spectroscopic properties of novel, photochromic indolinobenzospiropyran-based homopolymers prepared via ring-opening metathesis polymerization

Authors
Keum, Sam-RokAhn, Su-MiRoh, Se-JungMa, So-Young
Issue Date
6월-2010
Publisher
ELSEVIER SCI LTD
Keywords
Photochromic indolinobenzospiropyran; Homopolymer; Ring-opening metathesis polymerization; Grubbs' catalyst; Number-average molecular weights
Citation
DYES AND PIGMENTS, v.86, no.1, pp.74 - 80
Indexed
SCIE
SCOPUS
Journal Title
DYES AND PIGMENTS
Volume
86
Number
1
Start Page
74
End Page
80
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/116368
DOI
10.1016/j.dyepig.2009.12.002
ISSN
0143-7208
Abstract
Three types of novel photochromic indolinobenzospiropyran-based homopolymers were prepared via the ring-opening metathesis polymerization of the strained bicyclic indolinobenzospiropyran derivative. The homopolymers were soluble in common organic solvents and displayed unusually high polydispersity as determined by gel permeation chromatographic analysis. UV-visible absorption spectroscopy analysis in solution revealed that the appealing photochromic behaviour exhibited by the respective monomers was retained. (C) 2009 Elsevier Ltd. All rights reserved.
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