The synthesis and spectroscopic properties of novel, photochromic indolinobenzospiropyran-based homopolymers prepared via ring-opening metathesis polymerization
- Authors
- Keum, Sam-Rok; Ahn, Su-Mi; Roh, Se-Jung; Ma, So-Young
- Issue Date
- 6월-2010
- Publisher
- ELSEVIER SCI LTD
- Keywords
- Photochromic indolinobenzospiropyran; Homopolymer; Ring-opening metathesis polymerization; Grubbs' catalyst; Number-average molecular weights
- Citation
- DYES AND PIGMENTS, v.86, no.1, pp.74 - 80
- Indexed
- SCIE
SCOPUS
- Journal Title
- DYES AND PIGMENTS
- Volume
- 86
- Number
- 1
- Start Page
- 74
- End Page
- 80
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/116368
- DOI
- 10.1016/j.dyepig.2009.12.002
- ISSN
- 0143-7208
- Abstract
- Three types of novel photochromic indolinobenzospiropyran-based homopolymers were prepared via the ring-opening metathesis polymerization of the strained bicyclic indolinobenzospiropyran derivative. The homopolymers were soluble in common organic solvents and displayed unusually high polydispersity as determined by gel permeation chromatographic analysis. UV-visible absorption spectroscopy analysis in solution revealed that the appealing photochromic behaviour exhibited by the respective monomers was retained. (C) 2009 Elsevier Ltd. All rights reserved.
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