Catalytic Conversion of 1,2-Dichlorobenzene Over Mesoporous Materials from Zeolite
- Authors
- Lee, Hyung Ik; Kim, Ji Man; Lee, Jai-Young; Park, Young-Kwon; Jeon, Jong-Ki; Yim, Jin-Heong; Park, Sung Hoon; Lee, Kyung-Jin; Kim, Seung-Soo; Jeong, Kwang-Eun
- Issue Date
- 5월-2010
- Publisher
- AMER SCIENTIFIC PUBLISHERS
- Keywords
- Mesoporous Material from Zeolite (MMZ); Oxidation; 1,2-Dichlorobenzene
- Citation
- JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.10, no.5, pp.3639 - 3642
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
- Volume
- 10
- Number
- 5
- Start Page
- 3639
- End Page
- 3642
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/116541
- DOI
- 10.1166/jnn.2010.2295
- ISSN
- 1533-4880
- Abstract
- In this study, 1,2-dichlorobenzene (DCB), an important precursor of PCDDs and PCDFs, was chosen as a suitable model compound for the catalyzed deep oxidation of dioxin. The recently developed mesoporous materials from zeolites (MMZ) were used for the first time as a support for an oxidation catalyst. The catalytic oxidation of 1,2-dichlorobenzene over Pt/MMZ was carried out, and the catalytic activity was compared with that of Pt/gamma-Al2O3, Pt/Al-MCM-41 and Pt/Beta catalysts. Pt/MMZ showed the highest catalytic activity among the catalysts tested. Interestingly, the catalytic activity of Pt/MMZ was maintained (>40%) at low temperatures (250 degrees C) at which the other catalysts showed extremely low activity (<5%). The high catalytic activity of Pt/MMZ was attributed to both the sufficient acidity and mesoporosity of the MMZ support.
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Collections - College of Engineering > Department of Materials Science and Engineering > 1. Journal Articles
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