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New type of ruthenium sensitizers with a triazole moiety as a bridging group

Authors
Paek, SanghyunBaik, ChulKang, Moon-sungKang, HongsukKo, Jaejung
Issue Date
15-3월-2010
Publisher
ELSEVIER SCIENCE SA
Keywords
Dye; DSSC; Ru-complex
Citation
JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.695, no.6, pp.821 - 826
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume
695
Number
6
Start Page
821
End Page
826
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/116801
DOI
10.1016/j.jorganchem.2009.12.021
ISSN
0022-328X
Abstract
A new type of ruthenium sensitizers JK-91 and JK-92 with a triazole moiety as a bridging group were designed and synthesized in an attempt to increase the pi-conjugated system. Two compounds work as highly efficient sensitizers for the dye-sensitized nanocrystalline TiO2 solar cell. Under standard AM 1.5 sunlight, the sensitizer JK-91 yielded a short-circuit photocurrent density of 12.55 mA/cm(2), an open-circuit voltage of 0.73 V, and a fill factor of 0.73, corresponding to an overall conversion efficiency of 6.75%. (C) 2010 Elsevier B.V. All rights reserved.
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