New type of ruthenium sensitizers with a triazole moiety as a bridging group
- Authors
- Paek, Sanghyun; Baik, Chul; Kang, Moon-sung; Kang, Hongsuk; Ko, Jaejung
- Issue Date
- 15-3월-2010
- Publisher
- ELSEVIER SCIENCE SA
- Keywords
- Dye; DSSC; Ru-complex
- Citation
- JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.695, no.6, pp.821 - 826
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Volume
- 695
- Number
- 6
- Start Page
- 821
- End Page
- 826
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/116801
- DOI
- 10.1016/j.jorganchem.2009.12.021
- ISSN
- 0022-328X
- Abstract
- A new type of ruthenium sensitizers JK-91 and JK-92 with a triazole moiety as a bridging group were designed and synthesized in an attempt to increase the pi-conjugated system. Two compounds work as highly efficient sensitizers for the dye-sensitized nanocrystalline TiO2 solar cell. Under standard AM 1.5 sunlight, the sensitizer JK-91 yielded a short-circuit photocurrent density of 12.55 mA/cm(2), an open-circuit voltage of 0.73 V, and a fill factor of 0.73, corresponding to an overall conversion efficiency of 6.75%. (C) 2010 Elsevier B.V. All rights reserved.
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Collections - College of Science and Technology > Department of Advanced Materials Chemistry > 1. Journal Articles
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