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Structural defects in LiCoO2 studied by Li-7 nuclear magnetic relaxation
- Authors
- Kim, J. S.; Lee, K. W.; Kweon, J. J.; Lee, Cheol Eui; Kim, K.; Lee, J.; Noh, S. J.; Kim, H. S.
- Issue Date
- 8-2월-2010
- Publisher
- AMER INST PHYSICS
- Keywords
- diffusion; lithium compounds; nuclear magnetic resonance; paramagnetic resonance; spin-lattice relaxation; vacancies (crystal); X-ray diffraction
- Citation
- APPLIED PHYSICS LETTERS, v.96, no.6
- Indexed
- SCIE
SCOPUS
- Journal Title
- APPLIED PHYSICS LETTERS
- Volume
- 96
- Number
- 6
- ISSN
- 0003-6951
- Abstract
- Microscopic environments and dynamics in LiCoO2 systems were probed by Li-7 nuclear magnetic relaxation measurements with regard to the structural defects as revealed by x-ray diffraction and electron spin resonance measurements. Thus, the structural defects of differing degrees, associated with Li vacancies, were well accounted for in the temperature-dependent spin-lattice relaxation rate analysis, and in the structural and dynamical inhomogeneity as derived from the relaxation patterns.
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