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Novel Optical/Electrochemical Selective 1,2,3-Triazole Ring-Appended Chemosensor for the Al3+ Ion

Authors
Kim, Sang HoonChoi, Hong SeokKim, JoohoonLee, Suk JoongQuang, Duong TuanKim, Jong Seung
Issue Date
5-Feb-2010
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.12, no.3, pp.560 - 563
Indexed
SCIE
SCOPUS
Journal Title
ORGANIC LETTERS
Volume
12
Number
3
Start Page
560
End Page
563
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/117001
DOI
10.1021/ol902743s
ISSN
1523-7060
Abstract
A chemosensor (1) bearing a 1,2,3-triazole ring spacer was synthesized for the selective detection of Al3+ with respect to dual optical and electrochemical changing events. The addition of Al+ ions to 1 induced a significant change in fluorescence intensity, attributable to ICT and CHEF effects from the 1,2,3-triazole ring. The electrochemical behavior of 1 in the presence of the Al3+ ion was significantly altered compared with those of the other metal cations tested.
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