Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane
- Authors
- Park, Jinhyung; Kwon, Young Bum; Yang, Kyungmo; Rhee, Hakjune; Yoon, Cheol Min
- Issue Date
- Feb-2010
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- Baylis-Hillman acetates; allyltributylstannane; bis-pi-allylpalladium; 1,5-diene; allylation
- Citation
- SYNTHESIS-STUTTGART, no.4, pp.661 - 665
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNTHESIS-STUTTGART
- Number
- 4
- Start Page
- 661
- End Page
- 665
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/117130
- DOI
- 10.1055/s-0029-1218612
- ISSN
- 0039-7881
- Abstract
- Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPh3)(4) or Pd(dba)(2) as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-dienes in good to high yields.
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Collections - College of Science and Technology > Department of Advanced Materials Chemistry > 1. Journal Articles
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